Hey Seth,
Good to hear you are getting it where you want it. I like your thinking.....no balance knob? Adjust the speakers! A perfect example of why we call this a hobby.
I did mean a hand held SPL meter. They can remain accurate when our ears are telling us something's off. I pull my Radio Shack SPL Meter out every now and then, just to see if my ears are telling me the truth. (also to calibrate the HT)
Good thinking about checking the tubes. I don't have any tube gear, so I have no knowledge about such things. But it sounds logical.
My La Scala's are toed in also and the left one, slightly more than the right. I also have the left speaker gain 7db's higher than the right, as I sit on the right side of the room. It gives me great stereo imaging/separation and a large sound-stage.
Be careful moving those beasts around, the older I get the heavier they get!!! 
Dennie
Happiness makes up in height for what it lacks in length.
- Robert Frost
Of all noises, I think music is the least disagreeable.
- Samuel Johnson
1979 La Scala's I bought them off the original owner, he actually had tears in his eyes as he counted my money. Now I know why!!! Mitsubishi RPTV WS48313, Infocus 4805, Pioneer Elite Vsx-41, Hafler DH-200, ADCOM GFA 7607, Oppo Dv970HD, Paramax 5100, AudioControl C-101 III, ELAC Mirachord 40 Turntable, (HT speakers)Kef Q7's, Kef Q10c, Ci130Ds, Ci130QR, SVS 20-39 PC Plus, HT Master MX-800